How to Derive Conservation of Charge in Electrodynamics
How to Derive Conservation of Charge in Electrodynamics
The continuity equation is an expression of conservation of a quantity, an important principle in physics. In electrodynamics, an important quantity that is conserved is charge. Moreover, charge is not only globally conserved (the total charge in the universe stays the same), but is locally conserved as well. We derive a continuity equation that expresses this local conservation of charge both from basic principles and as a consequence of Maxwell's equations.
Steps

Derivation from Basic Principles

Begin with charge Q ( t ) {\displaystyle Q(t)} Q(t) in a volume V {\displaystyle V} V. We want to show that charge is locally conserved in this system. That is, any charge initially inside the volume that is found outside of the volume must have passed through the boundary. Below, ρ ( r , t ) {\displaystyle \rho (\mathbf {r} ,t)} \rho ({\mathbf {r}},t) is the charge density, the source of the electromagnetic field. Q = ∫ V ρ d V {\displaystyle Q=\int _{V}\rho \mathrm {d} V} Q=\int _{{V}}\rho {\mathrm {d}}V

Account for current I {\displaystyle I} I. Recall that current is the time rate of change of charge. Below, J {\displaystyle \mathbf {J} } {\mathbf {J}} is the current density. Integrating J {\displaystyle \mathbf {J} } {\mathbf {J}} over the entire surface gives current. However, there is an additional negative sign attached to the expression below, because when charge flows out as described by a positive derivative, it corresponds to a decrease in charge. I = d Q d t = − ∮ S J ⋅ d S {\displaystyle I={\frac {\mathrm {d} Q}{\mathrm {d} t}}=-\oint _{S}\mathbf {J} \cdot \mathrm {d} \mathbf {S} } I={\frac {{\mathrm {d}}Q}{{\mathrm {d}}t}}=-\oint _{{S}}{\mathbf {J}}\cdot {\mathrm {d}}{\mathbf {S}}

Rewrite current in terms of charge density. d Q d t = d d t ∫ V ρ d V = ∫ V ∂ ρ ∂ t d V {\displaystyle {\begin{aligned}{\frac {\mathrm {d} Q}{\mathrm {d} t}}&={\frac {\mathrm {d} }{\mathrm {d} t}}\int _{V}\rho \mathrm {d} V\\&=\int _{V}{\frac {\partial \rho }{\partial t}}\mathrm {d} V\end{aligned}}} {\begin{aligned}{\frac {{\mathrm {d}}Q}{{\mathrm {d}}t}}&={\frac {{\mathrm {d}}}{{\mathrm {d}}t}}\int _{{V}}\rho {\mathrm {d}}V\\&=\int _{{V}}{\frac {\partial \rho }{\partial t}}{\mathrm {d}}V\end{aligned}}

Invoke the divergence theorem for the surface integral. Recall that the divergence theorem states that the flux penetrating a closed surface S {\displaystyle S} S bounding a volume V {\displaystyle V} V is equal to the divergence of a vector field inside that volume. − ∮ S J ⋅ d S = − ∫ V ( ∇ ⋅ J ) d V {\displaystyle -\oint _{S}\mathbf {J} \cdot \mathrm {d} \mathbf {S} =-\int _{V}(\nabla \cdot \mathbf {J} )\mathrm {d} V} -\oint _{{S}}{\mathbf {J}}\cdot {\mathrm {d}}{\mathbf {S}}=-\int _{{V}}(\nabla \cdot {\mathbf {J}}){\mathrm {d}}V

Equate the two previous expressions and set it to zero. We can put the expression under one integral because we are integrating over the same object. ∫ V ∂ ρ ∂ t d V + ∫ V ( ∇ ⋅ J ) d V = 0 ∫ V ( ∂ ρ ∂ t + ∇ ⋅ J ) d V = 0 {\displaystyle {\begin{aligned}\int _{V}{\frac {\partial \rho }{\partial t}}\mathrm {d} V+\int _{V}(\nabla \cdot \mathbf {J} )\mathrm {d} V&=0\\\int _{V}\left({\frac {\partial \rho }{\partial t}}+\nabla \cdot \mathbf {J} \right)\mathrm {d} V&=0\end{aligned}}} {\begin{aligned}\int _{{V}}{\frac {\partial \rho }{\partial t}}{\mathrm {d}}V+\int _{{V}}(\nabla \cdot {\mathbf {J}}){\mathrm {d}}V&=0\\\int _{{V}}\left({\frac {\partial \rho }{\partial t}}+\nabla \cdot {\mathbf {J}}\right){\mathrm {d}}V&=0\end{aligned}}

Arrive at the continuity equation. Because the only quantity for which the integral is 0, is 0 itself, the expression in the integrand can be set to 0. This leads us to the continuity equation describing local conservation of charge. ∂ ρ ∂ t = − ∇ ⋅ J {\displaystyle {\frac {\partial \rho }{\partial t}}=-\nabla \cdot \mathbf {J} } {\frac {\partial \rho }{\partial t}}=-\nabla \cdot {\mathbf {J}}

Derivation from Maxwell's Equations

Begin with the Ampere-Maxwell Law. We want to show that conservation of charge can be readily derived from Maxwell's equations. Below, we write the Ampere-Maxwell Law in differential form. ∇ × B = μ 0 J + μ 0 ϵ 0 ∂ E ∂ t {\displaystyle \nabla \times \mathbf {B} =\mu _{0}\mathbf {J} +\mu _{0}\epsilon _{0}{\frac {\partial \mathbf {E} }{\partial t}}} \nabla \times {\mathbf {B}}=\mu _{{0}}{\mathbf {J}}+\mu _{{0}}\epsilon _{{0}}{\frac {\partial {\mathbf {E}}}{\partial t}}

Take the divergence of both sides. There are two things to recognize here. First, the divergence of a curl is always 0, so the left side vanishes. Second, given well-behaved vector functions (in this case, vector functions on simply-connected domains), partial derivatives commute. In physics and engineering, we almost always deal with continuous, well-behaved functions, so this symmetry of mixed partials holds. ∇ ⋅ ( ∇ × B ) = μ 0 ∇ ⋅ J + μ 0 ϵ 0 ∇ ⋅ ∂ E ∂ t μ 0 ϵ 0 ∂ ∂ t ( ∇ ⋅ E ) = − μ 0 ∇ ⋅ J {\displaystyle {\begin{aligned}\nabla \cdot (\nabla \times \mathbf {B} )&=\mu _{0}\nabla \cdot \mathbf {J} +\mu _{0}\epsilon _{0}\nabla \cdot {\frac {\partial \mathbf {E} }{\partial t}}\\\mu _{0}\epsilon _{0}{\frac {\partial }{\partial t}}(\nabla \cdot \mathbf {E} )&=-\mu _{0}\nabla \cdot \mathbf {J} \end{aligned}}} {\begin{aligned}\nabla \cdot (\nabla \times {\mathbf {B}})&=\mu _{{0}}\nabla \cdot {\mathbf {J}}+\mu _{{0}}\epsilon _{{0}}\nabla \cdot {\frac {\partial {\mathbf {E}}}{\partial t}}\\\mu _{{0}}\epsilon _{{0}}{\frac {\partial }{\partial t}}(\nabla \cdot {\mathbf {E}})&=-\mu _{{0}}\nabla \cdot {\mathbf {J}}\end{aligned}}

Recall Gauss' Law. ∇ ⋅ E = ρ ϵ 0 {\displaystyle \nabla \cdot \mathbf {E} ={\frac {\rho }{\epsilon _{0}}}} \nabla \cdot {\mathbf {E}}={\frac {\rho }{\epsilon _{0}}} By substituting Gauss' Law and simplifying, we recover the continuity equation describing conservation of charge. ∂ ρ ∂ t = − ∇ ⋅ J {\displaystyle {\frac {\partial \rho }{\partial t}}=-\nabla \cdot \mathbf {J} } {\frac {\partial \rho }{\partial t}}=-\nabla \cdot {\mathbf {J}}

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